Note on free current versus bound current
The electric current that arises in the simplest textbook situations would be classified as "free current"—for example, the current that passes through a wire or battery. In contrast, "bound current" arises in the context of bulk materials that can be magnetized and/or polarized. (All materials can to some extent.)When a material is magnetized (for example, by placing it in an external magnetic field), the electrons remain bound to their respective atoms, but behave as if they were orbiting the nucleus in a particular direction, creating a microscopic current. When the currents from all these atoms are put together, they create the same effect as a macroscopic current, circulating perpetually around the magnetized object. This magnetization current JM is one contribution to "bound current".
The other source of bound current is bound charge. When an electric field is applied, the positive and negative bound charges can separate over atomic distances in polarizable materials, and when the bound charges move, the polarization changes, creating another contribution to the "bound current", the polarization current JP.
The total current density J due to free and bound charges is then:
with Jf the "free" or "conduction" current density.
All current is fundamentally the same, microscopically. Nevertheless, there are often practical reasons for wanting to treat bound current differently from free current. For example, the bound current usually originates over atomic dimensions, and one may wish to take advantage of a simpler theory intended for larger dimensions. The result is that the more microscopic Ampère's law, expressed in terms of B and the microscopic current (which includes free, magnetization and polarization currents), is sometimes put into the equivalent form below in terms of H and the free current only.
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